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1 article(s) from Alissandratos, Apostolos

Biocatalysis for the application of CO₂ as a chemical feedstock

Apostolos Alissandratos and
Christopher J. Easton

Beilstein J. Org. Chem. 2015, 11, 2370–2387, doi:10.3762/bjoc.11.259

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Graphical Abstract

Figure 1: Biocatalytic routes for conversion of CO₂ into compounds with carbon in the reduced oxidation state...

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Figure 2: Carbonic anhydrase-catalysed rapid interconversion of CO₂ and HCO₃⁻ in living systems.

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Scheme 1: The Calvin cycle for fixation of CO₂ with RuBisCO.

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Scheme 2: The reductive TCA cycle with CO₂ fixation enzymes designated.

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Scheme 3: The Wood–Ljungdahl pathway for generation of acetyl-CoA through reduction of CO₂ to formate and CO....

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Scheme 4: The acyl-CoA carboxylase pathways for autotrophic CO₂ fixation. ACC: acetyl-CoA/propionyl-CoA carbo...

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Figure 3: RuBisCO CO₂-fixing bypass installed in E. coli and S. cerevisiae to increase carbon flux toward pro...

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Scheme 5: Integrated biocatalytic system for carboxylation of phosphoenolpyruvate (19), using PEPC and carbon...

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Scheme 6: PEPC and pyruvate carboxylase catalysed carboxylation of pyruvate backbone for the generation of ox...

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Scheme 7: Decarboxylase catalysed carboxylation of (a) phenol derivatives, (b) indole and (c) pyrrole.

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Figure 4: Formate dehydrogenase (FDH) catalysed reversible reduction of CO₂ to formate with electron donor re...

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Figure 5: Sequential generation of formate, formaldehyde and methanol from CO₂ using reducing equivalents sou...

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Figure 6: Hydrogen storage as formic acid through biocatalytic hydrogenation of CO₂ and subsequent on-demand ...

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Figure 7: Schematic showing required flow of reducing equivalents for CO₂ fixation through biotechnological a...

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Review

Published 01 Dec 2015

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Biocatalysis for the application of CO2 as a chemical feedstock

Biocatalysis for the application of CO₂ as a chemical feedstock